| Data | Hora | Adversário | Local | Resultado | Competição |
|---|---|---|---|---|---|
| 21.08.2032 | 00:00 | Andorra | A | 0 – 3 | La Liga |
| 28.08.2032 | 00:00 | Elche | H | 3 – 0 | La Liga |
| 04.09.2032 | 00:00 | Atlético Madrid | A | 0 – 1 | La Liga |
| 11.09.2032 | 00:00 | Girona | H | – | La Liga |
| 17.09.2032 | 20:00 | Partizan | A | – | Champions League |
| 18.09.2032 | 00:00 | Villarreal | A | – | La Liga |
| 19.09.2032 | 20:00 | Zeleznicar Pancevo | A | – | Conference League |
| 25.09.2032 | 00:00 | Sevilla | H | – | La Liga |
| 01.10.2032 | 20:00 | AZ | H | – | Champions League |
| 02.10.2032 | 00:00 | Athletic Bilbao | A | – | La Liga |
| 03.10.2032 | 20:00 | Fiorentina | A | – | Conference League |
| 09.10.2032 | 00:00 | Rayo Vallecano | A | – | La Liga |
| 16.10.2032 | 00:00 | Mallorca | H | – | La Liga |
| 22.10.2032 | 20:00 | Borussia Dortmund | A | – | Champions League |
| 23.10.2032 | 00:00 | Celta | A | – | La Liga |
| 24.10.2032 | 20:00 | Dinamo Zagreb | H | – | Conference League |
| 30.10.2032 | 00:00 | Barcelona | H | – | La Liga |
| 05.11.2032 | 20:00 | Borussia Dortmund | H | – | Champions League |
| 06.11.2032 | 00:00 | Deportivo La Coruña | A | – | La Liga |
| 07.11.2032 | 20:00 | Dinamo Zagreb | A | – | Conference League |
| 13.11.2032 | 00:00 | Osasuna | H | – | La Liga |
| 20.11.2032 | 00:00 | Málaga | A | – | La Liga |
| 26.11.2032 | 20:00 | Partizan | H | – | Champions League |
| 27.11.2032 | 00:00 | Valencia | H | – | La Liga |
| 28.11.2032 | 20:00 | Zeleznicar Pancevo | H | – | Conference League |
| 04.12.2032 | 00:00 | Gijón | A | – | La Liga |
| 10.12.2032 | 20:00 | AZ | A | – | Champions League |
| 11.12.2032 | 00:00 | Betis | A | – | La Liga |
| 12.12.2032 | 20:00 | Fiorentina | H | – | Conference League |
| 18.12.2032 | 00:00 | Racing Santander | H | – | La Liga |
| 25.12.2032 | 00:00 | Espanyol | A | – | La Liga |
| 01.01.2033 | 00:00 | Andorra | H | – | La Liga |
| 08.01.2033 | 00:00 | Elche | A | – | La Liga |
| 15.01.2033 | 00:00 | Atlético Madrid | H | – | La Liga |
| 22.01.2033 | 00:00 | Girona | A | – | La Liga |
| 29.01.2033 | 00:00 | Villarreal | H | – | La Liga |
| 05.02.2033 | 00:00 | Sevilla | A | – | La Liga |
| 12.02.2033 | 00:00 | Athletic Bilbao | H | – | La Liga |
| 19.02.2033 | 00:00 | Rayo Vallecano | H | – | La Liga |
| 26.02.2033 | 00:00 | Mallorca | A | – | La Liga |
| 05.03.2033 | 00:00 | Celta | H | – | La Liga |
| 12.03.2033 | 00:00 | Barcelona | A | – | La Liga |
| 19.03.2033 | 00:00 | Deportivo La Coruña | H | – | La Liga |
| 26.03.2033 | 00:00 | Osasuna | A | – | La Liga |
| 02.04.2033 | 00:00 | Málaga | H | – | La Liga |
| 09.04.2033 | 00:00 | Valencia | A | – | La Liga |
| 16.04.2033 | 00:00 | Gijón | H | – | La Liga |
| 23.04.2033 | 00:00 | Betis | H | – | La Liga |
| 30.04.2033 | 00:00 | Racing Santander | A | – | La Liga |
| 07.05.2033 | 00:00 | Espanyol | H | – | La Liga |